Bronze Patina and Corrosion contamination on surface before laser cleaning
Ikmanda Roswati
Ikmanda RoswatiPh.D.Indonesia
Ultrafast Laser Physics and Material Interactions
Published
Dec 16, 2025

Bronze Patina and Corrosion Contamination

Bronze-patina contamination, it arises from oxidation of copper-tin alloys in bronze when exposed to moist air and pollutants, thus forming adherent green-brown layers that alter surface appearance. This patina shows earthy color and porous texture, it distinguishes from similar contaminants by adhering tightly on bronze while spreading unevenly on brass surfaces and thinly on copper, so chemical bonding resists mechanical scraping and poses key removal challenges. Laser cleaning applies precise energy pulses to ablate the layer selectively, thus restoring underlying metal without heat damage, and surface already exhibits integrity after treatment.

Safety Information

Critical safety data for laser removal operations

Fire/Explosion Risk
low
Toxic Gas Risk
moderate
Visibility Hazard
moderate

Required Personal Protective Equipment

Respiratory Protection
PAPR
Eye Protection
goggles
Skin Protection
gloves

Hazardous Fumes Generated

CompoundConcentrationExposure LimitHazard ClassStatus
Copper Oxide Fume5 mg/m³0.1 mg/m³irritant⚠️ Exceeds Limit
Tin Oxide Fume2 mg/m³2 mg/m³irritant✓ Within Limit
Lead Oxide Fume0.05 mg/m³0.05 mg/m³toxic✓ Within Limit

Ventilation Requirements

Air Changes Per Hour
10
Exhaust Velocity
0.5 m/s
Filtration Type
HEPA

Particulate Generation

Respirable Fraction
70%
Size Range
0.1 - 10 μm

Substrate Compatibility Warnings

  • Lead content in bronze alloys may generate toxic lead oxide fumes
  • Chloride-containing patinas may produce chlorine gas when heated
  • Sulfur-containing compounds in corrosion may produce sulfur oxides