

Ikmanda RoswatiPh.D.Indonesia
Ultrafast Laser Physics and Material InteractionsPublished
Dec 16, 2025
Bronze Patina and Corrosion Contamination
Bronze-patina contamination, it arises from oxidation of copper-tin alloys in bronze when exposed to moist air and pollutants, thus forming adherent green-brown layers that alter surface appearance. This patina shows earthy color and porous texture, it distinguishes from similar contaminants by adhering tightly on bronze while spreading unevenly on brass surfaces and thinly on copper, so chemical bonding resists mechanical scraping and poses key removal challenges. Laser cleaning applies precise energy pulses to ablate the layer selectively, thus restoring underlying metal without heat damage, and surface already exhibits integrity after treatment.
Safety Information
Critical safety data for laser removal operations
Fire/Explosion Risk
low
Toxic Gas Risk
moderate
Visibility Hazard
moderate
Required Personal Protective Equipment
Respiratory Protection
PAPR
Eye Protection
goggles
Skin Protection
gloves
Hazardous Fumes Generated
| Compound | Concentration | Exposure Limit | Hazard Class | Status |
|---|---|---|---|---|
| Copper Oxide Fume | 5 mg/m³ | 0.1 mg/m³ | irritant | ⚠️ Exceeds Limit |
| Tin Oxide Fume | 2 mg/m³ | 2 mg/m³ | irritant | ✓ Within Limit |
| Lead Oxide Fume | 0.05 mg/m³ | 0.05 mg/m³ | toxic | ✓ Within Limit |
Ventilation Requirements
Air Changes Per Hour
10
Exhaust Velocity
0.5 m/s
Filtration Type
HEPA
Particulate Generation
Respirable Fraction
70%
Size Range
0.1 - 10 μm
Substrate Compatibility Warnings
- •Lead content in bronze alloys may generate toxic lead oxide fumes
- •Chloride-containing patinas may produce chlorine gas when heated
- •Sulfur-containing compounds in corrosion may produce sulfur oxides

