

Alessandro MorettiPh.D.Italy
Laser-Based Additive ManufacturingPublished
Dec 16, 2025
Electroless Nickel Plating Contamination
Nickel-plating contamination, it manifests as thin metallic deposits from electrochemical processes, where nickel ions adhere tenaciously to substrates during plating operations gone awry. This layer, distinct from oxide scales or organic residues by its uniform conductivity and corrosion resistance, behaves differently across metals: on steel, it bonds strongly, enhancing durability yet complicating separation, whereas on aluminum it induces galvanic corrosion that weakens the base, and on copper it merges seamlessly, promoting heat transfer but risking delamination. Removal challenges arise from its persistent adhesion, influenced from environmental factors like humidity, yet laser cleaning proves effective, as the beam selectively ablates the nickel through precise vaporization, preserving underlying integrity without mechanical stress.
Safety Information
Critical safety data for laser removal operations
Fire/Explosion Risk
low
Toxic Gas Risk
moderate
Visibility Hazard
moderate
Required Personal Protective Equipment
Respiratory Protection
PAPR
Eye Protection
goggles
Skin Protection
full_suit
Hazardous Fumes Generated
| Compound | Concentration | Exposure Limit | Hazard Class | Status |
|---|---|---|---|---|
| Nickel | 0.5-5.0 mg/m³ | 0.1 mg/m³ | toxic | ✓ Within Limit |
| Phosphorus compounds (as phosphine) | 0.05-0.5 mg/m³ | 0.14 mg/m³ | toxic | ✓ Within Limit |
| Nickel carbonyl | 0.001-0.01 mg/m³ | 0.001 mg/m³ | toxic | ✓ Within Limit |
Ventilation Requirements
Air Changes Per Hour
15
Exhaust Velocity
0.5-1.0 m/s
Filtration Type
HEPA
Particulate Generation
Respirable Fraction
80%
Size Range
0.1 - 10 μm
Substrate Compatibility Warnings
- •Thermal decomposition may release toxic nickel compounds - ensure adequate ventilation
- •Phosphorus content in electroless nickel can form phosphine gas under thermal stress
- •Residual plating solutions may react with laser energy

