

Yi-Chun LinPh.D.Taiwan
Laser Materials ProcessingPublished
Dec 16, 2025
Chromium Oxide Pitting Contamination
Chrome-pitting forms when localized chromium oxide layer breaks down on plated surfaces because of environmental exposure and corrosion, so surface degradation happens in small pits. This contamination shows unique pitting patterns distinct from uniform rust or scaling, where isolated spots appear without spreading widely, and it behaves differently on chrome-plated steel by deepening quickly during cleaning, while on stainless steel, pits resist less but still challenge uniformity. Key removal issues arise from substrate damage risk, yet laser cleaning works effectively because precise pulses target oxide breakdown so contaminants ablate cleanly without affecting base material.
Safety Information
Critical safety data for laser removal operations
Fire/Explosion Risk
low
Toxic Gas Risk
moderate
Visibility Hazard
moderate
Required Personal Protective Equipment
Respiratory Protection
PAPR
Eye Protection
goggles
Skin Protection
full_suit
Hazardous Fumes Generated
| Compound | Concentration | Exposure Limit | Hazard Class | Status |
|---|---|---|---|---|
| Chromium(III) Oxide | 5 mg/m³ | 0.5 mg/m³ | toxic | ⚠️ Exceeds Limit |
| Chromium(VI) Oxide | 0.8 mg/m³ | 0.005 mg/m³ | carcinogenic | ⚠️ Exceeds Limit |
| Iron Oxide | 15 mg/m³ | 5 mg/m³ | irritant | ⚠️ Exceeds Limit |
Ventilation Requirements
Air Changes Per Hour
12
Exhaust Velocity
0.5 m/s
Filtration Type
HEPA
Particulate Generation
Respirable Fraction
70%
Size Range
0.1 - 10 μm
Substrate Compatibility Warnings
- •Laser parameters must be optimized to minimize chromium(VI) formation
- •Avoid overheating substrate to reduce toxic fume generation
- •Containment required for chromium(VI) regulated material

