UV Photodegradation / Polymer Chalking contamination on surface before laser cleaning
Ikmanda Roswati
Ikmanda RoswatiPh.D.Indonesia
Ultrafast Laser Physics and Material Interactions
Published
Dec 16, 2025

UV Photodegradation / Polymer Chalking Contamination

UV-chalking contamination, it arises from photodegradation under ultraviolet exposure, where polymer chains fragment on the surface and thus form a white chalky residue that scatters and adheres as a powdery film. This residue distinguishes itself from dust or oxidation marks through its brittle texture that flakes easily under touch and pure white matte color, contrasting with sticky grime or yellowish patina, while on materials like ABS and polycarbonate it builds thickly and cracks during flexing, yet on nylon and polypropylene it develops sparse spots that roughen texture over time, so removal challenges include embedding into pores that worsens coverage with mechanical wiping or chemical dissolution damaging the base. Laser cleaning addresses these issues effectively, as pulses target the residue selectively and vaporize it without heat spread to the substrate, thus restoring surface uniformity already on delicate layers like acrylic or redwood.

Safety Information

Critical safety data for laser removal operations

Fire/Explosion Risk
low
Toxic Gas Risk
moderate
Visibility Hazard
moderate

Required Personal Protective Equipment

Respiratory Protection
half_mask
Eye Protection
goggles
Skin Protection
gloves

Hazardous Fumes Generated

CompoundConcentrationExposure LimitHazard ClassStatus
Carbon Monoxide5 mg/m³29 mg/m³toxic✓ Within Limit
Formaldehyde1.2 mg/m³0.37 mg/m³carcinogenic⚠️ Exceeds Limit
Acetaldehyde0.8 mg/m³45 mg/m³irritant✓ Within Limit
Volatile Organic Compounds (VOCs)15 mg/m³100 mg/m³irritant✓ Within Limit

Ventilation Requirements

Air Changes Per Hour
12
Exhaust Velocity
0.5 m/s
Filtration Type
carbon

Particulate Generation

Respirable Fraction
70%
Size Range
0.1 - 10 μm

Substrate Compatibility Warnings

  • UV laser interaction may generate ozone near work surface
  • Polymer substrates may produce hydrogen cyanide if containing nitrogen compounds
  • Chlorinated polymers may produce phosgene gas under thermal decomposition

UV Photodegradation / Polymer Chalking surface magnification

Before Treatment

Surface shows contamination from uv photodegradation / polymer chalking affecting material appearance and properties.

After Treatment

Post-cleaning reveals restored surface with uv photodegradation / polymer chalking successfully removed through precise laser ablation.