

Yi-Chun LinPh.D.Taiwan
Laser Materials ProcessingPublished
Dec 16, 2025
Paint Primer Layers Contamination
Primer-coating contamination forms when zinc-rich and epoxy-based layers degrade on metal surfaces after environmental exposure, creating adhesive buildup that bonds tightly to substrate. Unlike rust, which flakes loosely, this contamination exhibits sticky resilience and uneven thickness, so it distinguishes by requiring targeted removal to avoid surface scarring. On steel, adhesion persists strongly while on aluminum and galvanized metal, peeling occurs faster because of weaker interfacial links, yet challenges arise from potential heat-induced cracking during cleaning. Laser cleaning succeeds so because focused pulses vaporize coating selectively, preserving underlying material integrity.
Safety Information
Critical safety data for laser removal operations
Fire/Explosion Risk
low
Toxic Gas Risk
moderate
Visibility Hazard
moderate
Required Personal Protective Equipment
Respiratory Protection
half_mask
Eye Protection
goggles
Skin Protection
gloves
Hazardous Fumes Generated
| Compound | Concentration | Exposure Limit | Hazard Class | Status |
|---|---|---|---|---|
| Carbon Monoxide | 5-50 mg/m³ | 29 mg/m³ | toxic | ✓ Within Limit |
| Carbon Dioxide | 900-5000 mg/m³ | 9000 mg/m³ | toxic | ✓ Within Limit |
| Formaldehyde | 0.5-5.0 mg/m³ | 0.37 mg/m³ | carcinogenic | ✓ Within Limit |
| Volatile Organic Compounds (VOCs) | 10-100 mg/m³ | 100 mg/m³ | irritant | ✓ Within Limit |
| Hydrogen Chloride | 1-10 mg/m³ | 2 mg/m³ | corrosive | ✓ Within Limit |
Ventilation Requirements
Air Changes Per Hour
10
Exhaust Velocity
0.5 m/s
Filtration Type
carbon
Particulate Generation
Respirable Fraction
70%
Size Range
0.1 - 10 μm
Substrate Compatibility Warnings
- •Thermal decomposition may generate hazardous fumes from paint additives
- •Chlorinated compounds in some primers may produce corrosive gases
- •Heavy metal pigments (lead, chromium) may become airborne

