Carbon Dioxide laser cleaning visualization showing process effects
Yi-Chun Lin
Yi-Chun LinPh.D.Taiwan
Laser Materials Processing
Published
Jan 6, 2026

Carbon Dioxide Compound

Carbon Dioxide Compound safety information for laser cleaning. Health hazards, exposure limits, and protective equipment requirements.

Chemical Properties

Chemical Identity

CAS Number
124-38-9
Formula
CO₂
Molecular Weight
44.01 g/mol

Exposure Limits Comparison

Health Effects

Asphyxiation At High Concentration
Yes
Respiratory Stimulation
Yes
Narcosis
Yes
Generally Non Toxic
Yes
Detection Monitoring
SensorTypes
  • Infrared (NDIR)
  • Electrochemical
  • Thermal conductivity
DetectionRange
0-50,000 ppm typical (0-5%)
AlarmSetpoints
Low
5000 ppm (0.5%) - OSHA TWA/NIOSH REL
High
10,000 ppm (1%) - physiological effects begin
Evacuate
40,000 ppm (4%) - NIOSH IDLH
ColorimetricTubes
  • Dräger CO2 0.01%/a
  • Gastec 2L
  • Kitagawa 126
AnalyticalMethods
MethodTechniqueDetectionLimit
NIOSH 6603NDIR (Non-dispersive infrared)50 ppm
Detector tubesColorimetric0.01%
OdorThreshold
Not applicable - odorless at all concentrations. No warning property. MUST use instruments.
Environmental Impact
AquaticToxicity
Low direct toxicity. LC50 (fish): >100 mg/L. Acidifies water (forms carbonic acid). High levels suffocate aquatic life.
Biodegradability
Not applicable (natural component of carbon cycle).
Bioaccumulation
Does not bioaccumulate.
SoilMobility
High mobility as gas. Absorbed by alkaline soils forming carbonates.
AtmosphericFate
Major greenhouse gas. Atmospheric residence: 30-95 years. Essential for photosynthesis. Removed by plants and ocean absorption.
OzoneDepletion
false
GlobalWarmingPotential
1 (reference gas)
ReportableReleases
Water
Not reportable
Air
Not reportable (natural atmospheric component)
Ppe Requirements
Respiratory
SCBA for >5% (50,000 ppm) or oxygen-deficient atmospheres. Not required for normal ambient levels.
Eye Protection
Safety glasses for dry ice handling. No protection needed for gas.
Skin Protection
Insulated gloves for liquid/solid CO2 (dry ice) - cryogenic hazard. No protection needed for gas at normal levels.
Reactivity
Stability
Stable under normal conditions.
Polymerization
Will not polymerize
IncompatibleMaterials
  • Reactive metals (cesium, sodium, potassium)
  • Metal acetylides
  • Strong bases (forms carbonates)
  • Ammonia (forms ammonium carbamate)
HazardousDecomposition
  • Carbon dioxide (already stable)
  • Carbon monoxide (only at very high temperatures)
ConditionsToAvoid
  • High heat (cylinder explosion)
  • Reactive metals
ReactivityHazard
Generally non-reactive. Reacts with strong bases. May react with reactive metals. Solid CO2 causes embrittlement of some materials.
Regulatory Classification
UnNumber
UN1013 (compressed gas), UN1845 (solid/dry ice)
DotHazardClass
2.2 (Non-flammable gas)
DotLabel
Non-flammable Gas
NfpaCodes
Health
1
Flammability
0
Reactivity
0
Special
SA (Simple Asphyxiant)
EpaHazardCategories
  • Simple asphyxiant
  • Cryogenic hazard (dry ice)
SaraTitleIii
false

Contaminants That Produce Carbon Dioxide

Carbon Dioxide is produced as a complete combustion byproduct when laser energy fully oxidizes carbonaceous contaminants. Paint, oil, grease, and organic residue ablation generates CO2 alongside water vapor. While non-toxic at typical cleaning concentrations, CO2 monitoring is recommended in confined spaces to prevent oxygen displacement.

Chemical Properties

Molecular formula, CAS number, molecular weight, and chemical structure
Type
chemical_properties
Id
carbon-dioxide-physical-data

Physical Properties

Chemical and physical characteristics
BoilingPoint
-78.5°C (-109.3°F) sublimes at 1 atm
MeltingPoint
-56.6°C (-69.9°F) @ 5.1 atm
VaporPressure
830 psi @ 20°C
VaporDensity
1.52 (Air=1)
SpecificGravity
1.56 (solid @ -79°C), 0.77 (liquid @ 0°C)
FlashPoint
Not applicable (non-flammable)
AutoignitionTemp
Not applicable
ExplosiveLimits
Not applicable (does not burn)
Appearance
Colorless gas, white solid (dry ice)
Odor
Odorless

Alternative Names

Synonyms and chemical identifiers
Synonyms
  • CO2
  • Carbonic anhydride
  • Carbonic acid gas
  • Dry ice (solid)
CommonTradeNames
  • Dry ice
OtherIdentifiers
RtecsNumber
FF6400000
EcNumber
204-696-9
PubchemCid
280

Health Effects

Adverse health impacts from exposure to this compound
Route
inhalation
Effect
Asphyxiation due to oxygen displacement, leading to unconsciousness and potential death at concentrations >10%
Severity
severe
Onset
immediate
Route
inhalation
Effect
Headache, dizziness, and increased heart rate at concentrations 3-5%
Severity
moderate
Onset
short-term
Route
inhalation
Effect
Respiratory acidosis and hyperventilation at prolonged exposure to elevated levels
Severity
high
Onset
long-term
Route
eye_contact
Effect
Mild irritation from direct high-pressure exposure
Severity
low
Onset
immediate
Route
skin_contact
Effect
Frostbite or irritation if in liquefied form (dry ice)
Severity
moderate
Onset
immediate

Personal Protective Equipment

Required safety equipment for handling this compound
Respiratory
SCBA for >5% (50,000 ppm) or oxygen-deficient atmospheres. Not required for normal ambient levels.
Skin
Insulated gloves for liquid/solid CO2 (dry ice) - cryogenic hazard. No protection needed for gas at normal levels.
Eye
Safety glasses for dry ice handling. No protection needed for gas.
MinimumLevel
Level D for normal operations, Level B for confined spaces or high concentrations
SpecialNotes
Simple asphyxiant - displaces oxygen. Heavier than air - accumulates in low areas. Dry ice causes frostbite. Physiological effects >1% concentration.

Exposure Limits

OSHA, NIOSH, and ACGIH exposure thresholds
OshaPelPpm
5000
OshaPelMgM3
9000
NioshRelPpm
5000
NioshRelMgM3
9000
AcgihTlvPpm
5000
AcgihTlvMgM3
9000
WorkplaceExposure
OshaPel
twa8Hr: 5000 ppm
stel15Min: null
ceiling: 30000 ppm
NioshRel
twa8Hr: 5000 ppm
stel15Min: 30000 ppm
ceiling: null
idlh: 40,000 ppm (4%)
AcgihTlv
twa8Hr: 5000 ppm
stel15Min: 30000 ppm
ceiling: null
BiologicalExposureIndices

Storage Requirements

Safe storage conditions and compatibility
TemperatureRange
Store cylinders <52°C. Dry ice requires insulated storage <-78°C.
Ventilation
Good ventilation essential. Outdoor storage preferred for large quantities. Monitor oxygen levels in storage areas.
Incompatibilities
  • Reactive metals (cesium, sodium, potassium)
  • Metal acetylides
  • Bases (reacts forming carbonates)
ContainerMaterial
Steel cylinders for compressed gas. Insulated containers for dry ice.
Segregation
None required. Keep away from reactive metals.
QuantityLimits
Cylinders per fire code. Dry ice quantities limited by storage capacity.
SpecialRequirements
Cylinder restraints mandatory. Oxygen monitoring in storage areas. Post "SIMPLE ASPHYXIANT" signs. Adequate ventilation critical. Never store in confined spaces without ventilation and O2 monitoring.

Emergency Response

Procedures for spills, exposure, and incidents
FireHazard
Non-flammable. Used as fire suppressant. Cylinders may explode when heated.
FireSuppression
Not applicable. CO2 extinguishes fires. If cylinder in fire, cool with water spray from maximum distance or evacuate - explosion hazard.
SpillProcedures
Liquid/dry ice release: Ventilate area immediately. Evacuate low-lying areas - CO2 heavier than air. Monitor oxygen levels. Do not touch dry ice - frostbite.
ExposureImmediateActions
Remove to fresh air immediately. If not breathing, give artificial respiration. Administer 100% oxygen. Seek medical attention if symptoms persist. For dry ice contact: treat as frostbite - warm affected area gradually.
EnvironmentalHazards
Greenhouse gas. Contributes to ocean acidification. Generally non-toxic to wildlife at normal atmospheric levels.
SpecialHazards
SIMPLE ASPHYXIANT - displaces oxygen. Heavier than air - accumulates in pits, tanks, confined spaces. Physiological effects: >1% increased respiration, >5% headache/dizziness, >10% unconsciousness, >20-30% death. ODORLESS - no warning. Dry ice causes severe frostbite.

Regulatory Classification

DOT, UN, and NFPA hazard classifications
UnNumber
UN1013 (compressed gas), UN1845 (solid/dry ice)
DotHazardClass
2.2 (Non-flammable gas)
DotLabel
Non-flammable Gas
NfpaCodes
Health
1
Flammability
0
Reactivity
0
Special
SA (Simple Asphyxiant)
EpaHazardCategories
  • Simple asphyxiant
  • Cryogenic hazard (dry ice)
SaraTitleIii
false

Environmental Impact

Toxicity, biodegradability, and environmental fate
AquaticToxicity
Low direct toxicity. LC50 (fish): >100 mg/L. Acidifies water (forms carbonic acid). High levels suffocate aquatic life.
Biodegradability
Not applicable (natural component of carbon cycle).
Bioaccumulation
Does not bioaccumulate.
SoilMobility
High mobility as gas. Absorbed by alkaline soils forming carbonates.
AtmosphericFate
Major greenhouse gas. Atmospheric residence: 30-95 years. Essential for photosynthesis. Removed by plants and ocean absorption.
OzoneDepletion
false
GlobalWarmingPotential
1 (reference gas)
ReportableReleases
Water
Not reportable
Air
Not reportable (natural atmospheric component)

FAQ

Common Questions and Answers
What are the safe exposure limits for CO₂ during laser cleaning operations, and how can I monitor them?
Occupational exposure limits for CO₂ as an asphyxiant are set by OSHA at 5,000 ppm (0.5%) as an 8-hour time-weighted average (TWA), with a short-term exposure limit of 30,000 ppm (3%) for no more than 10 minutes, and levels above 4% (40,000 ppm) can cause immediate oxygen displacement and loss of consciousness. To monitor, use portable CO₂ gas detectors or multi-gas monitors calibrated for real-time ppm readings in your workspace, especially in enclosed or poorly ventilated areas during laser cleaning. Always ensure oxygen levels remain above 19.5% and integrate alarms that trigger at or below these limits to prevent asphyxiation risks.

Detection & Monitoring

Methods for detecting and measuring this compound
SensorTypes
  • Infrared (NDIR)
  • Electrochemical
  • Thermal conductivity
DetectionRange
0-50,000 ppm typical (0-5%)
AlarmSetpoints
Low
5000 ppm (0.5%) - OSHA TWA/NIOSH REL
High
10,000 ppm (1%) - physiological effects begin
Evacuate
40,000 ppm (4%) - NIOSH IDLH
ColorimetricTubes
  • Dräger CO2 0.01%/a
  • Gastec 2L
  • Kitagawa 126
AnalyticalMethods
  • [object Object]
  • [object Object]
OdorThreshold
Not applicable - odorless at all concentrations. No warning property. MUST use instruments.

Reactivity

Chemical reactivity and incompatibilities
Stability
Stable under normal conditions.
Polymerization
Will not polymerize
IncompatibleMaterials
  • Reactive metals (cesium, sodium, potassium)
  • Metal acetylides
  • Strong bases (forms carbonates)
  • Ammonia (forms ammonium carbamate)
HazardousDecomposition
  • Carbon dioxide (already stable)
  • Carbon monoxide (only at very high temperatures)
ConditionsToAvoid
  • High heat (cylinder explosion)
  • Reactive metals
ReactivityHazard
Generally non-reactive. Reacts with strong bases. May react with reactive metals. Solid CO2 causes embrittlement of some materials.

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